Home Chemistry Heterocyclic Building Blocks Thiophenes 4H-Cyclopenta[2,1-B:3,4-B']Dithiophene
Electrophilic Aromatic Substitution (EAS): Like many aromatic compounds, CPDT can undergo EAS reactions where an electrophile (an electron-deficient species) substitutes a hydrogen atom attached to the aromatic ring. This can lead to the introduction of various functional groups.
Nucleophilic Aromatic Substitution (SNAr): CPDT can also undergo SNAr reactions where a nucleophile substitutes a leaving group on the aromatic ring. This reaction is more common in electron-deficient aromatic systems.
Cross-Coupling Reactions: CPDT can be utilized in various cross-coupling reactions (e.g., Suzuki-Miyaura, Stille, Heck reactions) to form C-C bonds. These reactions are particularly important in the synthesis of conjugated polymers for electronic applications.
Oxidation Reactions: CPDT contains sulfur atoms which are susceptible to oxidation. Various oxidizing agents can be used to convert the sulfur atoms to sulfoxides or sulfones.
Reduction Reactions: CPDT can be reduced to form various intermediates or derivatives. For instance, it can be reduced to the corresponding dithiol.
Grignard Reactions: CPDT can react with Grignard reagents to form various organometallic compounds.
Heterocyclic Synthesis: CPDT can be used as a starting material for the synthesis of more complex heterocyclic compounds.
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6-Bromo-4,4-dihexyl-4H-cyclopenta[2,1-b:3,4-b']dithiophene-2-carbaldehyde
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2,6-Dibromo-4,4-dihexyl-4H-cyclopenta[1,2-b:5,4-b']dithiophene
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(4,4-Bis(2-ethylhexyl)-4H-cyclopenta[1,2-b:5,4-b']dithiophene-2,6-diyl)bis(trimethylstannane)
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2,6-Dibromo-4,4-bis(6-bromohexyl)-4H-cyclopenta[1,2-b:5,4-b']dithiophene
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4,4-Dihexyl-4H-cyclopenta[1,2-b:5,4-b']dithiophene
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2,6-Dibromo-4H-cyclopenta[1,2-b:5,4-b']dithiophene
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4,4-Bis(2-ethylhexyl)-4H-cyclopenta[1,2-b:5,4-b']dithiophene
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2,6-Dibromo-4,4-bis(2-ethylhexyl)-4H-cyclopenta[1,2-b:5,4-b']dithiophene
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